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New Brunswick is the only province in Canada that is officially bilingual English and French. Francophones speak a dialect known as Acadian French. Acadian is not related to Quebec French, since Acadia's history is separated from the one of Quebec. Acadian French speakers are instantly recognizable by their charming and strongly trilled r.
Near Moncton and in other urban areas, a distinct English-French creole language known as chiaque is spoken. It's frowned upon as "bad French" by Francophones and "bad English" by Anglophones, but it's popular among young people. Some effort is being made to rehabilitate chiaque, with a nascent literature and support organizations.
The English / French split within the province is approximately a Northeast / Southwest split. Despite the split, English is spoken throughout the province. French speakers may struggle to find fluent French speakers in the Southwest of the province.
See also: French phrasebook